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For Free Radical
Polymerization

BlocBuilder® RC-50 for Free Radical Polymerization

BlocBuilder ® RC-50 is a reactivity controller, containing the remarkable new nitroxide radical SG-1, which enables the control of organic peroxide free radical polymerizations. This nitroxide-mediated technology is the basis of several Arkema patents and can be used to control the polymerization of any unsaturated resin.

BlocBuilder ® RC-50 Controller provides the following benefits to composite laminate manufacturers:

  • Reduced logistics costs - room temperature shipping and storage
  • Reduced inventory obsolescence costs - extended product shelf-life
  • Homogeneous blending - easy dispersion into resin systems
  • Reduced overall material costs - reduction of required initiator volume
  • Reduced resin scrap - extended pot-life for initiated resins without addiitonal inhibitors (see chart below)
  • Reduced resin viscosity (up to 50%) and wet-out time - elevated temperature resin (up to 105º F)
  • Simple trigger to start gelation - cure-on-demand (through heat energy)
  • Improved laminate mechanical properties - reduced void content in cured laminate

Click on each for larger view:

Unlike traditional inhibitors that consume up to 50% of the free radicals from the initiators, BlocBuilder® RC-50 Controller "caps" the styril-free radicals to form a dormant species.

formation of dormant styril-free radicals using BlocBuilder RC-50 Contriller

This molecule will remain dormant until sufficient heat energy ( ~145º F / 60º C ) is applied to the initiated resin to uncap the free radicals. Because all of the free radicals are still available, curing is faster and complete, with lower residual styrene.

BlocBuilder® RC-50 Controller has demonstrated significant value in the following closed mold composite manufacturing processes:

  • Pultrusion
  • Filament winding
  • Resin transfer molding & vacuum infusion processing
  • Sheet/bulk molding compounds
  • Prepreg materials

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Arkema's flexible business model supports diverse marketplace requirements. Depending on your needs and interest, you can purchase either the BlocBuilder® RC-50 Controller or a custom blend with alternative diluents, initiators and/or co-promoters.



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